Organic compounds

4.1.3 Fuels

4.3 Polymers

Organic compounds

Series Structure Properties Uses
Alkanes Name: _ane
Functional group: -C-C-
General formula: CnH2n+2
Alkanes make up most of the hydrocarbons in crude oil Fuels
Cracking into alkenes by vaporising it and passing it over a hot catalyst of aluminium oxide or mixing it with steam at around 850 °C so that it thermally decomposes
Alkenes Name: _ene
Functional group: -C=C-
General formula: CnH2n
React with bromine water, turning it from orange to colourless1 Fuels
Hydrating into alcohols by reacting it with steam in the presence of a catalyst of concentrated sulfuric acid
Alcohols Name: _ol
Functional group: -OH
General formula: CnH2n+1OH
First three dissolve in water to form neutral1 solutions
React with sodium to produce hydrogen2
Burn in air
Fuels & solvents
Oxidising into carboxylic acids by chemical oxidising agents or microbial action
Ethanol is the main alcohol in alcoholic drinks
Carboxylic acids Name: _oic acid
Functional group: -COOH
General formula: Cn-1H2n-1COOH
Dissolve in water to form acidic solutions, but do not ionise completely so are weak acids React with alcohols in the presence of an acid catalyst to form esters
Ethanoic acid is the main component of vinegar
Esters Name: _yl _oate
Functional group: -COO
General formula: Cn-1H2n-1COOCmH2m+1
Volatile
Have distinctive smells
Flavourings
Perfumes

  1. This is due to bromine reacting with the ethene to form a vicinal dibromoalkane: -CH=CH- + Br2 → -BrCH-CHBr-
  2. Actually acidic
  3. The products are hydrogen and a sodium alkoxide salt: 2R-OH + 2Na → 2R-ONa + H2